UPDATE (8-3-2007): As this is one of the most popular posts on tartare, I am going to do a post soon with a guacamole recipe that incorporates a few techniques to fight off the browning. Now, back to your regularly scheduled program.
Some time ago, in a discussion about guacamole, the subject of discoloration of avocados came up. Avocados, as even the most casual of cooks would know, brown quickly. All fruits that have little or no acid content have this quality. The person I was talking to then told me about a secret they have for keeping their avocados from going brown on them: when making guacamole, place the avocado pits in the finished product and it will prevent them from turning brown. In the interest of being polite, I smiled and said that I had never heard about that practice before.
I keep a list of things like this that either don't sound correct or seem questionable and invariably, I come across something confirming or debunking. Cut to: I was perusing Mark Bittman's How To Cook Everything, a most worthwhile cookbook for any cook. I think it is best for aspiring cooks. Its easy recipes and light food science compliment each other well. Anyway, I chanced upon Bittman's guacamole recipe which includes the following technique:
"Garnish and serve, or tuck the pit(s) back into the mixture, cover with plastic wrap, and refrigerate for up to 4 hours (this will keep the guacamole from turning brown). Remove the pit(s) before garnishing and serving."
When I think about it, it just doesn't seem to make sense. Avocado browns as a result of enzymatic browning. Violating the outside skin and cutting up the fruit releases enzymes which break down into dark brown compounds (actually related to melanin). But somehow, avocado pits must be able to generate a force-field over the guacamole and defeat the action of the enzymes. Wow. Avocados must have some magic pits.
Well, dinner last tonight involved a really pretty guacamole/crab/creme fraiche/baby greens stack for the salad, so I saw my opportunity to test this practice out. I separated some of the guacamole and put it aside with an avocado pit and saran wrap; the other half simply had saran wrap pressed down on it so that there were no air bubbles. And you know what? Don't bother with the pits. Given the underlying science, every single bit of the guacamole would have to be in contact or close proximity with the pit for this to work, if it did indeed work. For guacamole, the best practice note is this: make your guacamole as close to service as is practical, ensure that you have used a reasonable amount of acid in it, and for gosh-sakes -- cover that stuff up by pressing the saran into the surface so you minimize air bubbles.
Call this one debunked, but here is a fairness disclaimer: Mark Bittman's book is really good, a must own and I am sure that his guacamole is wonderful. All cooks have a few little odd beliefs like this. I remember reading a recipe by a well-known and skilled French chef who still believed that meat had pores or something that became seared closed by browning on the outside, which, of course, is not true at all. Browning develops flavors through Maillard reactions and retaining juices has to do with other best practices, but not browning. However, being wrong about the underlying science doesn't preclude superior results and pointing it out doesn't mean that my results would be superior.
UPDATED: My friend Roger C suggests that ascorbic acid's antioxidant properties would be a great way to hold the color. Makes sense to me.